Neither of them have to come first (except perhaps alphabetically). You could go only to a university, or only to a college. In the cases where you would go to both, college would probably come first, because you might transfer from a two-year college to a university, or go from a college to a university for grad school, but it is also possible to move the other way, from a university to a state college or something, so there really isn't a set order.
a
V - Think keyboard
V comes before B.
Yes, you must be enrolled in classes to play. That is why they are called a STUDENT- athlete. Academics comes before athletics.
a millisecond comes before a second
58622 comes 1 before 58623, 58613 comes 10 before 58623.
T comes before U, and V comes after U.
Stanford University. University of California, Berkeley, comes close.
699 comes before and 701 comes after
what comes before b.c
5 comes before 6.
leo comes before virgo.