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s p d f are spectral lines sharp, principal, diffuse and fine seen in atomic emission spectra. These are also letters assigned to atomic orbitals which are defined by the azimuthal quantum number l which in turn is related to the principal quantum number n. These are sometimes referred to as sub-shells. K, L, M, N are another name for the electron shells defined by the principal quantum number n. K is 1, L is 2 etc.

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Q: What difrrent betweenspdf and klmn?
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