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Since there are lots of different kinds of liquids and they have various properties, there is no one technique that would be used in all cases, but it is very common to separate liquids based upon differences in boiling point, so you can heat a mixture and collect the vapor which may contain only one of the liquids; this process is called distillation. If the liquids are immiscible, it's trivial: use centrifugation and/or a separatory funnel.

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