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The question is somewhat unclear, so my answer may be off.

Energy levels in discussion of atomic structure typically refer to the structure of the electron cloud.

Around an atoms nucleus are a series of orbitals in which electrons can be stored - they require greater amounts of stored energy to contain at higher orbitals. As such, each orbital fills from the innermost ring out.

See http://en.wikipedia.org/wiki/Atomic_orbital for the discussion of atomic orbitals on wikipedia. Each orbital refers to a specific energy level.

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