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Calcium is actually the main cation (positively charged ion) responsible for muscle contraction. Most people think it is Sodium or Potassium. Sodium is an anion (negatively charged ion) which controls your body's saturation (all the way down to the cellular level) and also aids in transporting minerals. What happens when you are dehydrated? Your muscles cramp up. Potassium is a cation which creates electricity. In muscle movement, sodium and potassium create a channel in which sodium rushes in and potassium rushes out causing the muscle fiber membrane to become more positively charged, triggering an action. This ultimately would not be possible without calcium, which starts the whole process. For more information check out the following link.

References: http://en.wikipedia.org/wiki/Muscle_contraction

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