It one of the titrations method to determine the permanent and temporary hardness of water.
Procedure;
step 1: standardise the edta solution
step 2: titrate against the hard water mixed with ebt until the colour changes from wine red to blue.
Then we can caluclate the normality using the formula
(n1) *(v1)=(n2)*(v2).
Posted by Krishna kanth yenumula.
why is the pH of the meadium important in EDTA titration
To determine concentration of EDTA.
we standardize edta to make the soln stable complex
We usually heat KSCN Fe solution before titration with EDTA so as to produce crystalline crust forms.
1. Direct Titration In direct titration, you simply add an indicator to the solution of the metal ion and titrate with EDTA. Before starting the titration,it is needed to check that the pH of the solution to obtain a good formation constant value and on the other hand indicator colour change as well. 2.Indiract titration EDTA can be used as titrant for anions. Anions can be precipitated with suitable metal ion. Filter and wash the ppt with proper solution. Then boil in excess EDTA to complex metal ion(ppt). Back titrate to determine how much metal ion you had. 3.Back Titration In a back titration an excess of EDTA is added to the metal ion solution, and the excess EDTA is titrated with a known concentration of a second metal ion. The second metal ion must form a weaker complex with EDTA than the analyte ion so the second metal does not displace the analyte ion from its complex with EDTA. 4.Displacement titration Here the analyte is treated with an excess of a second metal bound to EDTA. The analyte ion displaces the second metal from the EDTA complex, and then the second metal is titrated with EDTA.
u can use titration with EDTA or use flame atomic absorption.. but titration with EDTA is the easiest
why is the pH of the meadium important in EDTA titration
To determine concentration of EDTA.
eriochrome black T is an indicator for EDTA titration
we standardize edta to make the soln stable complex
during the complexometric titration using edta it is very necessary to maintain the ph of the solution near about 10 so we use ammonium chloride buffer if we will not use this buffer dring the titration ph of sol. will ho lower side
EDTA reacts to form so called 'one to one'-complexes with all bi- and tri-valent metal ions
We usually heat KSCN Fe solution before titration with EDTA so as to produce crystalline crust forms.
1. Direct Titration In direct titration, you simply add an indicator to the solution of the metal ion and titrate with EDTA. Before starting the titration,it is needed to check that the pH of the solution to obtain a good formation constant value and on the other hand indicator colour change as well. 2.Indiract titration EDTA can be used as titrant for anions. Anions can be precipitated with suitable metal ion. Filter and wash the ppt with proper solution. Then boil in excess EDTA to complex metal ion(ppt). Back titrate to determine how much metal ion you had. 3.Back Titration In a back titration an excess of EDTA is added to the metal ion solution, and the excess EDTA is titrated with a known concentration of a second metal ion. The second metal ion must form a weaker complex with EDTA than the analyte ion so the second metal does not displace the analyte ion from its complex with EDTA. 4.Displacement titration Here the analyte is treated with an excess of a second metal bound to EDTA. The analyte ion displaces the second metal from the EDTA complex, and then the second metal is titrated with EDTA.
eriochrome blact T
to maintain constant ph
During a precipitation titration an insoluble precipitate is formed.Complexometric titration is a type of volumetry which use as titrants EDTA or other similar reagents.