eriochome black T
eriochrome blact T
Indicator is added to zinc because firstly it combines with zinc and forms zinc-indicator complex and after addition of more EDTA to the complex , the zinc which was in the form of complex gave free indicator and forms Zn-EDTA complex and the free indicator gaves blue colour which indicates end point of titration.
why is the pH of the meadium important in EDTA titration
1. Direct Titration In direct titration, you simply add an indicator to the solution of the metal ion and titrate with EDTA. Before starting the titration,it is needed to check that the pH of the solution to obtain a good formation constant value and on the other hand indicator colour change as well. 2.Indiract titration EDTA can be used as titrant for anions. Anions can be precipitated with suitable metal ion. Filter and wash the ppt with proper solution. Then boil in excess EDTA to complex metal ion(ppt). Back titrate to determine how much metal ion you had. 3.Back Titration In a back titration an excess of EDTA is added to the metal ion solution, and the excess EDTA is titrated with a known concentration of a second metal ion. The second metal ion must form a weaker complex with EDTA than the analyte ion so the second metal does not displace the analyte ion from its complex with EDTA. 4.Displacement titration Here the analyte is treated with an excess of a second metal bound to EDTA. The analyte ion displaces the second metal from the EDTA complex, and then the second metal is titrated with EDTA.
çünkü öyle gerekti yeğen araştırıyorum bulursam yazarım neden =)
eriochrome blact T
eriochrome black T is an indicator for EDTA titration
Indicator is added to zinc because firstly it combines with zinc and forms zinc-indicator complex and after addition of more EDTA to the complex , the zinc which was in the form of complex gave free indicator and forms Zn-EDTA complex and the free indicator gaves blue colour which indicates end point of titration.
why is the pH of the meadium important in EDTA titration
1. Direct Titration In direct titration, you simply add an indicator to the solution of the metal ion and titrate with EDTA. Before starting the titration,it is needed to check that the pH of the solution to obtain a good formation constant value and on the other hand indicator colour change as well. 2.Indiract titration EDTA can be used as titrant for anions. Anions can be precipitated with suitable metal ion. Filter and wash the ppt with proper solution. Then boil in excess EDTA to complex metal ion(ppt). Back titrate to determine how much metal ion you had. 3.Back Titration In a back titration an excess of EDTA is added to the metal ion solution, and the excess EDTA is titrated with a known concentration of a second metal ion. The second metal ion must form a weaker complex with EDTA than the analyte ion so the second metal does not displace the analyte ion from its complex with EDTA. 4.Displacement titration Here the analyte is treated with an excess of a second metal bound to EDTA. The analyte ion displaces the second metal from the EDTA complex, and then the second metal is titrated with EDTA.
çünkü öyle gerekti yeğen araştırıyorum bulursam yazarım neden =)
u can use titration with EDTA or use flame atomic absorption.. but titration with EDTA is the easiest
we standardize edta to make the soln stable complex
EDTA reacts to form so called 'one to one'-complexes with all bi- and tri-valent metal ions
We usually heat KSCN Fe solution before titration with EDTA so as to produce crystalline crust forms.
to maintain constant ph
To determine concentration of EDTA.