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Hello.
addressing attorney and wife
Dr. and Mr. Smith.
Rabbi and Mrs.
Dr. and Mr. Smith
miss
Dear Mrs Ambassador..
vmrs
"Dr and Mrs Smith" is the correct salutation. (With Smith replaced with the correct surname)
Dear Judge Smith and Mr. Smith.
probabaly just a mrs. would suffise
The proper salutation for a man who is a doctor is Dr. David Jones or you can say Mr. David Jones, M.D. either way is ok. If the Doctor is married: Dr. David Jones & Mrs. Jones.