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85 wt. % of the structured water and 100 wt. % of solvated ion pairs' clusters in egg yolk from free-range hens (FH) are at temperatures lower than 298 K in special depositories where theese depositories shall be destroyed at temperatures >300 К. The small water clusters (Н2О)11±1 interact differently with the protein bases depending on the temperature of the eggs. The influence of captive breeding (CB) on the eggs biomatrix was shown and compared with that one of FH. CB eggs don't have any maximum of collapsed clusters at 300 K (egg-white) and 305 K (egg yolk). Additionally, the statistical cluster ensembles in CB eggs are stable up to 357 K whereas in FH eggs they depend on temperature. Comparing CB with FH it was found that for the first one the number of the main protein coils after the quarantine was highly reduced. The state of ovalbumin monomers, dimers and octamers and the state of their surroundings in biomatrices was discussed. Information about the water content in ovalbumin monomers and octamers and about the interaction of these protein associates with the surroundings is given too. The difference between the free-range and battery eggs biomatrices could be helpful to later investigations concerning long time space flights.

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12y ago

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