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What makes silicon a semiconductor?

Updated: 9/19/2023
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13y ago

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Elements have two bands.

One is Valence band and other is Conduction band.

Valence band contains electrons whereas the conduction band is empty.

The energy gap between them is called the forbidden gap.

In case of metals, this gap is very small or the bands overlap.

Therefore, the electrons are able to jump from the valence band to the conduction band and hence metal are able to conduct electricity and they are generally conductors.

In case of Non-Metals, the energy gap is very large and hence hence electrons are not able to move from valence band to conduction band.

Hence they are insulators.

But in case of elements like Silicon, Germanium this gap is between Metals and Non-Metals, hence few electrons are able to move from valence band to conduction band. Therefore they have some conductivity but it is low and hence they are called semiconductors.

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When in intrinsic semiconductor (pure silicon) addition of small amount of impurity of group V elements (arsenic, antimony, phosphorous) makes N-type semiconductor. V group elements provides one extra electron to silicon atom. so this makes negative charge and majority of electrons. so its called N-type.. And in P-type when in pure silicon addition of small amount of impurity of group III elements (boron, aluminum) makes the P-type. by adding IIIrd group elements they they accepts the electrons from the silicon atom since its trivalent elements so there will be vacancy of 1 electron in silicon lattice resulting the formation of "hole". This makes semiconductor positive charged semiconductor called P-type.