According to SOWPODS (the combination of Scrabble dictionaries used around the world) there are 8 words with the pattern --L-W. That is, five letter words with 3rd letter L and 5th letter W. In alphabetical order, they are:
ablow
aglow
allow
below
bylaw
pilaw
pilow
unlaw
sinew, elbow, shrew, askew, scrawny
I am thinking the word AFTER
maple, alder, aspen
35
Madam
E.M.P.T.Y. is a containing nothing with 5 letters
5
spanish dance ending in o
Today
Does he drink a whole liter of coffee every morning?
Third (exactly 5 letters)
first
Puppy