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Homemade silicone rubber is made by melting silicone until it turns into rubber form. Professionally, there are several ways to produce silicone rubber, most are a mixture of silicone, oxygen, carbon and hydrogen.
You can find silicone rubber anywhere. A trip to your local hardware store will yield the best results. But amazon carries thousands of pounds of silicone rubber on their website.
They are made out of silicone rubber
You can find a great selection of cheap silicone bracelets at www.reminderband.com
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Urethane rubber is actually not rubber. It is known as urethane elastomer and is cheaper than Silicone rubber. However, it does not last a long and requires the application of a release agent before every casting. It is cheaper than silicone rubber and has a higher tear strength.
Most plastic wristbands are created out of silicone rubber in factories, most of which are in Asia. Silicone rubber is placed into a mold, and solidifies. The mold would have the proper design which would then be passed on to the silicone rubber.
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"Rubber wristbands are commonly made from silicone-a durable synthetic resin. Silicone is rubber-like but unlike rubber, valued for being heat-resistant and latex-free."
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There are a lot of options for buying rubber bracelets / silicone wristbands. You can buy them online at Target or Amazon or if you need to get a custom wristband, you can try a site like MonkeyBands.com