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The energy in butane, or in any compound for that matter, is stored in the chemical bonds that hold the atoms together. It takes energy to break those bonds, and then energy is released when new bonds are formed. If the energy needed for burning butane is less than the energy generated when the new bonds are formed in CO2 and H2O, then you get useful energy being produced.

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Q: Where did the energy stored in butane come from?
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