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I don't know about herbs, but a spice called Cloves is often successfully used to control the pain of a toothache until someone can get to a dentist. It is often sold in pharmacies with names like 'toothache essence' or 'oil of cloves' or 'spirits of cloves'.

You put some on a cotton wool ball and apply to the painful area, keeping it in the mouth. It tastes horrible, but it certainly relieves the pain.

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Q: Which herbs are used for the relief of tooth ache?
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