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Which is a better electrophile singlet nitrene or triplet nitrene?
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∙ 11y ago
singlet
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∙ 11y ago
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In cross aldol condensation between aldehyde and ketone why aldehyde is always an electrophile?
Alkyl groups are electron donating (whereas hydrogen atoms aren't). A ketone has 2 alkyl groups attached to the carbonyl carbon, but an aldehyde has only 1 alkyl group attached to its carbonyl carbon. This gives the aldehyde carbon more positive charge character, which makes it a better electrophile than the ketone. Another factor is less stearic hindrence for carbonyl carbon of aldehyde as compare to ketones.
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In cross aldol condensation between aldehyde and ketone why aldehyde is always an electrophile?
Alkyl groups are electron donating (whereas hydrogen atoms aren't). A ketone has 2 alkyl groups attached to the carbonyl carbon, but an aldehyde has only 1 alkyl group attached to its carbonyl carbon. This gives the aldehyde carbon more positive charge character, which makes it a better electrophile than the ketone. Another factor is less stearic hindrence for carbonyl carbon of aldehyde as compare to ketones.
Do alkenes react with sulphuric acid?
Alkenes react with concentrated sulphuric acid in the cold to produce alkyl hydrogensulphates. Ethene reacts to give ethyl hydrogensulphate. CH2=CH2 + H2SO4 --> CH3CH2OSO2OH The structure of the product molecule is sometimes written as CH3CH2HSO4, but the version in the equation is better because it shows how all the atoms are linked up. You may also find it written as CH3CH2OSO3H.
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