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Why NO2 is bent in shape?

Updated: 9/16/2023
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11y ago

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NO2 is an odd electron molecule - it has 17 valence electrons. There is one unpaired electron which "sits" on the nitrogen. The VSEPR model deals specifically with electron pair repulsion so strictly you can't use it to predict the shape. However what you do is assume that the lone pair orbital is only half filled and is not as repulsive as a true lone pair. So treat it as AX2E compound and therefore bent, but as E is not so repulsive the ONO angle opens out to be greater than 1200, which is in fact true, its 134 0

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11y ago
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Q: Why NO2 is bent in shape?
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