ammonium oxalate is added to calcium carbonate because in the reaction between the two a crystal is formed that contain the Ca+2 ion. This is useful because if you have a sample of sodium carbonate with an unknown molarity you can use the oxalate to extract this calcium and determine what the molarity of the unknown solution was
(NH4)2C2O4 + CaCl2 ---> 2NH4Cl + CaC2O4
calcium oxalate precipitates only in basic solution
Ammonium oxalate is difunctional and so the normaility is 0.2N.
(NH4)2C2O4 is the chemical formula ammonium oxalate.
oxalate
Calcium carbonate is rather INsoluble, so there is no solution of it. I do not know why ammonium oxalate is added to a calcium carbonate solution. Calcium oxalate will then precipitate out of the solution. The ammonium and carbonate will create a weakly bond compound. Actually, more of the ammonium ion will be in solution as free ammonia and more of the carbonate ions will be in solution as free carbon dioxide. That is the nature of those two substances. So, you will have a solution that has a calcium oxalate precipitant on the bottom and is slowly giving off ammonia and carbon dioxide.
(NH4)2C2O4 + CaCl2 ---> 2NH4Cl + CaC2O4
(NH4)2C2O4(aq) + CaCl2(aq) yields CaC2O4 +2NH4Cl(aq)
calcium oxalate precipitates only in basic solution
Ca(NO3)2 + (NH4COO)2 = Ca(COO)2 + 2 NH4NO3 Calcium oxalate is a white precipitate.
Ammonium oxalate is difunctional and so the normaility is 0.2N.
Ammonium oxalate monohydrate is (NH4)2C2O4•H2O
(NH4)2C2O4 is the chemical formula ammonium oxalate.
oxalate
Formula of ammonium oxalate monohydrate: (NH4)2C2O4.H2O
mw : 134 /2= 67
In formol titration, amino acids with formaldehyde are titrated with NaOH to measure the amount of amino acids in the solution. Potassium is also necessary for this titration and is supplied by using potassium oxalate. If calcium is present, it will react with the NaOH to form Ca(OH)2. This will make it appear to need more of the NaOH solution (and overestimate the titration). Potassium oxalate will chelate the calcium, and prevent it from reacting (forming calcium oxalate).