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It's hard to get rid of heat in space, usually. There's no air for convection or conduction. All that is left is radiating the heat away. So it is best to be able to avoid picking up even more heat. The black tiles are highly heat resistant and insulative. The white tiles reflect most sunlight away. This prevents overheating and makes it easier to control the temperature. The cargo bay doors have radiators built into them to make radiating heat away even easier.

A side effect of this is that it is more noticable with telescopes.

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Q: Why are space shuttles white and not black?
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