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They DON'T explode when you pull the pin. There are three safeties on a grenade: the safety clip, the pin and the handle. The pin is the second safety you release.

When all three safeties have been released, there's a little plunger under the handle that ignites a delaying charge. When the charge burns down to the end of the fuze, it ignites a primer that causes the grenade's filler to explode.

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Q: Why do grenades explode when you pull the pin?
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