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It depends if you are you mixing light, or if you are mixing paint. Enough different colors of light, in the correct proportions, can make white. More than 2 or 3 colors of paint, no matter what the proportions, usually makes something like peanut butter.

The difference is the color system used. Light uses the positive system, where if you mix red, green, and blue light, you get white. But, with paints, the negative system applies, and if you mix cyan, yellow, and magenta, you get black.

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Q: Why do we get a murky color and not white when mixing the seven colors of the rainbow?
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