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By rotating the container of a free-running solid, the solid will "free run" and tumble while it is being poured out (transferred). This makes the transfer more easily accomplished. Many divided solids (sand or salt, for example) can become "sticky" or clump together due to moisture or other factors, and rotating a container while dumping them makes them "run out" more efficiently and smoothly.

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Q: Why do you rotate a container of free-running solid while transferring the solid?
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