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Cis/Trans Isomerism occurs when there are two different groups on each side of the C=C bond. In But-2-ene the Carbons with a double bond are each bonded to one C and one H whereas, in But-1-ene one end is bonded to carbon and Hydrogen, and one end is bonded to two hydrogens.

H [CH2]- CH3

\ /

C=C But-1-ene: One end bonded to two Hydrogens, One end bonded

/ \ to 1 x Carbon, 1 x Hydrogen

H [H]

H H

\ /

C=C cis But-2-ene: Both ends of double bond are bonded to, 1 x Carbon

/ \ 1 x Hydrogen, and biggest elements on each side

H3C CH3 (Carbon) are both on same side so cis or Z

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Waldo Ledner

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Q: Why does 2- butene have cis and trans isomers but 1- butene doesn't?
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