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There are two basic methods for decaffinating coffee. There is the Swiss water process, which involves a series of water rinses to rid the beans of caffeine. The other method is a chemical process, which is much more widely used because it's cheaper and more effective. I think it's quite likely that the chemicals used to "decaf" the coffee are reacting with the Bailey's.

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12y ago
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Q: Why does baileys curdle in decaf coffee?
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