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Because the xenon atom's electrons in its lower orbitals (5s and 5p) are promoted to a higher shell (5d). This allows the fluorine to bond with these unpaired electrons. Argon would have to promote 3s and 3p to 3d (too high of an energy gap).

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Q: Why does fluorine bond with xenon but not argon?
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Related questions

Which is more reactive fluorine oxygen or neon?

Fluorine even combines with argon, krypton, xenon, and radon. Even in dark, cool conditions, fluorine reacts explosively with hydrogen. http://en.wikipedia.org/wiki/Fluorine Fluorine even combines with argon, krypton, xenon, and radon. Even in dark, cool conditions, fluorine reacts explosively with hydrogen. http://en.wikipedia.org/wiki/Fluorine


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