When something is evaporating from your skin, it is the more energetic molecules that are escaping. This results in the average energy of the molecules left behind dropping. Temperature is a measure of the average energy of a group of molecules.
The bonds holding rubbing alcohol molecules together are not as great as the bonds holding water molecules together and so the molecules escape more often in the case of water molecules. This increases the cooling effect.
Rubbing alcohol feels cold when applied to the skin because it has a lower boiling point than body temperature. As it evaporates quickly upon contact with the skin, it absorbs heat from the surrounding area, giving a cooling sensation.
Rubbing alcohol contains isopropyl alcohol, which evaporates quickly and can lower the temperature of the skin, causing a cold sensation. This sensation may feel like a burning or stinging on sensitive areas like the scrotum. It is important to avoid applying rubbing alcohol to sensitive areas to prevent discomfort or irritation.
Ethanol feels cold when applied to the skin because it evaporates quickly, absorbing heat from the skin in the process. This rapid evaporation leads to a cooling sensation on the skin, similar to how rubbing alcohol or hand sanitizer may feel cold upon application.
Because alcohol evaporates easily, and sucks some heat from your hand as it does.
The liquid they put on your arm is rubbing, or isopropyl alcohol. They do this to sterilize your skin so that when they inject you the needle doesn't push any dirt or bacteria that may have been hanging out on the surface into your arm. The reason it feels cold is because isopropyl alcohol evaporates extremely fast because of its high vapor pressure and evaporation is a process that requires energy which causes a cooling sensation on your skin. Its the same reason sweat or water cool you off.
Green rubbing alcohol is used in the same ways that regular rubbing alcohol is used. It is used for first-aid like scrapes and cuts, but generally has additives like menthol oil to smell and feel tingly and minty.
When acetone evaporates, it feels cold because the process of evaporation requires energy. This energy is taken from the surrounding environment, including your skin, making it feel cold.
Ether is a form of alcohol - which evaporates very quickly. This takes heat away from your skin, and thus you feel cold in that area.
Rubbing alcohol should not be ingested in children AND adults, no matter if you are in perfect health, ingesting more than an ounce will make you feel the need to call 911
Water absorbs heat from its surrounding as it evaporates.
The hot water on your skin opens your pores, and makes you sweat. The sweat evaporates, taking body heat away - making you feel cold. When your body is cold - you shiver.
This is no longer an accepted treatment for fever or infectious disease as it used to be. Years ago this was an accepted way to lower a temp of an infant or child. Please note: this is no longer accepted. Alcohol fumes could overcome or kill a child. To reduce fever in a child (dangerous high fever) use only a tepid bath (water a couple degrees below body temperature which would feel cool to your elbow) or get directions from the pediatrician. ANY time an infant has fever, the doctor should always be contacted.But being cold or having rubbing alcohol on your skin that makes you feel cold can not cause pneumonia. See the related question below about being cold making you sick.