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Most things are more dense in their solid or frozen form, which would make them sink.

Water is quite unique in that when it freezes it actually becomes less dense. This is due to strong hydrogen bonding in water (ethanol also hydrogen bonds, but not as much). When the water molecules freeze they arrange themselves in a fairly ordered crystal to maximize the hydrogen bonding interactions. This is also why snowflakes show such amazing patterns.

The crystallized structure that water shows when it freezes is the real reason that ice is less dense than water. The structure of water and the way that the molecules attract when frozen, leads to a structure that contains voids where nothing is present. So literally it is like there are tiny air pockets in ice that you cannot get rid of.

See also the Web Links to the left of this answer.

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