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White chocolate is not chocolate, it is cocoa butter and has a lower burning point than chocolate. Depending on the microwave settings you may have caramelized (burnt) the sugar in the cocoa butter. You should use a lower microwave setting and do it in smaller increments to see if it melted but not burnt..

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8y ago
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14y ago

The brown color is a result of the chocolate burning.

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Q: Why does your white chocolate turn brown in microwave?
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