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Cold air sinks because it is more dense than warmer air. The warmer the air is the more energy the molecules have. The more energy the molecules have the more they vibrate. When the molecules vibrate they bounce into each other and push apart from each other, hence the warmer air is; the less dense it is (number of molecules per unit volume). So, colder air has less energy which means more molecules can fit into one space (because they are not bouncing off each other) which essentially makes it heavier.

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