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It is used in the barometer because it is the densest liquid known, requiring only 33 inches of Mercury to indicate atmospheric pressure. Water on the other hand would require 39 feet to indicate the same pressure.

It is used in thermometers for a different reason. The expansion of mercury is a stable amount. Meaning it changes in volume the same amount from 0 to 1 degrees as it does in volume from 100 to 101 degrees, making it a desirable fluid for scaling thermometers.

Presently in the US it is illegal to manufacture these devices using mercury.

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