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Unlike most substances, when water freezes, it forms a structure that is less dense than the liquid it is in equilibrium with (which is why ice floats on liquid water). It is also unusual in that the maximum density of the liquid reaches a minimum at a temperature ABOVE the freezing point - roughly 1.0000 g/cm3 at 4 °C - before it begins to increase as it approaches the freezing point. Water thus has a negative coefficient of thermal expansion between 0 °C and 4 °C and a zero coefficient right at 4 °C. Other substances have uniformly positive coefficients of thermal expansion.

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Q: Why is water strange in thermal expansion?
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