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I think that after heating within the first rang of temperature the crystalline structure dislocation happen and the gaps between the atoms increases more than the solid state. So that it will take time at first to reach this state then after this state is approached the time required to increase the temperature of the metal is less, but after certain time the metal reaches a liquid state. Consequently it will need to evaporate at the next phase so the temperature is settled down on a constant value because this phase needs a huge amount of energy to happen.

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Q: Why isothermal transformation diagram have C shape?
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