Ethers are used as solvent in Grignard reaction and not as catalyst. This is because if we use other solvents which have acidic hydrogen, Grignard reagent will decompose and the Grignard reaction will not proceed further.
You should really use anhydrous hexane; however, ethers can absorb large quantities of water; THF is completely miscible with water and will thus require extensive drying in order to get an anhydrous environment. Hexane absorbs very little water due to the unfavourable interactions between it and water. Therefore "non-anhydrous" hexane contains such a small quantity of water that the Grignard reagent formed will more than adequately dry the hexane.
No, ethers are generally less reactive than alcohols. Alcohols have a hydroxyl group (-OH) that can participate in various chemical reactions such as oxidation, dehydration, and nucleophilic substitution. Ethers, on the other hand, lack such a reactive functional group and are generally more inert.
Ethers are hydrogen bond acceptors, but not hydrogen bond donors, as are alcohols. Ethers are generally unreactive as solvents, for that reason. Because of the polarity of the O-H bond in alcohol, the hydrogen atom comes on and off readily, allowing alcohol to act as a solvent in many reactions.
Solubility. LAH is not soluble in other solvents which would otherwise be appropriate.
By definition, ethers must contain at least one oxygen atom.
You should really use anhydrous hexane; however, ethers can absorb large quantities of water; THF is completely miscible with water and will thus require extensive drying in order to get an anhydrous environment. Hexane absorbs very little water due to the unfavourable interactions between it and water. Therefore "non-anhydrous" hexane contains such a small quantity of water that the Grignard reagent formed will more than adequately dry the hexane.
due to its behaviours of complexes crown ethers they act as strong phase transfer catalyst.
yes...
No, ethers are generally less reactive than alcohols. Alcohols have a hydroxyl group (-OH) that can participate in various chemical reactions such as oxidation, dehydration, and nucleophilic substitution. Ethers, on the other hand, lack such a reactive functional group and are generally more inert.
Ethers are hydrogen bond acceptors, but not hydrogen bond donors, as are alcohols. Ethers are generally unreactive as solvents, for that reason. Because of the polarity of the O-H bond in alcohol, the hydrogen atom comes on and off readily, allowing alcohol to act as a solvent in many reactions.
Solubility. LAH is not soluble in other solvents which would otherwise be appropriate.
Brandon S. Stillwell has written: 'Reagent controlled asymmetric iodoetherification' -- subject(s): Marine organisms, Effect of chemicals on, Cyclic compounds, Ethers
Breaking the Ethers was created on 1997-03-01.
Though they are very similar to ethers, they are not ethers. They're sulfides.
By definition, ethers must contain at least one oxygen atom.
Wow! are they!?!?!?!?
yes