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Why brown turbidity found in titrating KMno4 with oxalic acid?
Brown turbidity in the titration of KMnO4 with oxalic acid may be due to the formation of manganese dioxide (MnO2). This reaction occurs in acidic conditions and indicates that the end point of the titration has been reached. MnO2 is insoluble and can appear as a brown precipitate, causing turbidity in the solution.
Why use h2so4 instead of hcl in titration of kmno4?
H2SO4 is typically used instead of HCl in the titration of KMnO4 because HCl can react with KMnO4 and form chlorine gas, which can interfere with the titration results. Additionally, H2SO4 provides the required acidic medium for the reaction to occur between KMnO4 and the analyte.
Why you add h2so4 to the kmno4 titration?
consider the balance chemical equation, suppose the reaction with oxalic acid 2MnO4- + 16H+ + 5C2O4 --> 2Mn+2 + 8H2O + 10CO2 Above reaction shows that the reaction requires a number of protons to occur, H2SO4 is the source of these protons.
Redox titrations of ferrous ion with KMnO4 why the HCl is not used in this reaction?
HCl is not used in redox titrations of ferrous ion with KMnO4 because it can react with KMnO4 and interfere with the titration process. HCl can reduce KMnO4, which would lead to inaccurate results by altering the equivalence point of the titration. Instead, a buffer solution is often used to maintain a constant pH during the titration.
Why HCL is not use to acidify KMnO4 soln in permanganometric titration?
HCl cannot be used to acidify KMnO4 solution in permanganometric titration because it will react with KMnO4 reducing it to MnO2, which interferes with the titration process and affects the accuracy of the results. Instead, dilute sulfuric acid (H2SO4) is typically used to acidify the KMnO4 solution, as it does not interfere with the redox reaction between KMnO4 and the analyte.
Why brown turbidity found in titrating KMno4 with oxalic acid?
Brown turbidity in the titration of KMnO4 with oxalic acid may be due to the formation of manganese dioxide (MnO2). This reaction occurs in acidic conditions and indicates that the end point of the titration has been reached. MnO2 is insoluble and can appear as a brown precipitate, causing turbidity in the solution.
Why is brown turbidity found in titrating KMnO4 solution with oxalic acid?
Brown turbidity in a titration of KMnO4 with oxalic acid typically arises from the formation of manganese(II) ions during the reaction. When KMnO4, which is purple, is reduced by oxalic acid, it produces manganese(II) ions, which can form a brown precipitate of manganese(IV) oxide (MnO2) in certain conditions. This turbidity indicates the presence of manganese species that are not fully soluble, often due to incomplete reduction or changes in pH during the titration.
Why use h2so4 instead of hcl in titration of kmno4?
H2SO4 is typically used instead of HCl in the titration of KMnO4 because HCl can react with KMnO4 and form chlorine gas, which can interfere with the titration results. Additionally, H2SO4 provides the required acidic medium for the reaction to occur between KMnO4 and the analyte.
Why we ad sulpheric acid with oxalic acid?
we add sulpheric acid with oxalic acid to stable the ions when titrated against KMNO4
Why you add h2so4 to the kmno4 titration?
consider the balance chemical equation, suppose the reaction with oxalic acid 2MnO4- + 16H+ + 5C2O4 --> 2Mn+2 + 8H2O + 10CO2 Above reaction shows that the reaction requires a number of protons to occur, H2SO4 is the source of these protons.
Why KmnO4 is used as self indicator?
As we all know that the potassium permanganate (KMnO4) is the dark purple color solution ...and in titration it become colorless ....so when the titration is completed ...and the other single drop of KMnO4 solution produce pinkish colour in a beaker ...which indicate that the reaction was completed just a single drop before .. we use indicator in a a reaction in order to indicate ...but we dont used indicator in titration with KMnO4 because it also indicate us by changing its color ...colorless to pink
Redox titrations of ferrous ion with KMnO4 why the HCl is not used in this reaction?
HCl is not used in redox titrations of ferrous ion with KMnO4 because it can react with KMnO4 and interfere with the titration process. HCl can reduce KMnO4, which would lead to inaccurate results by altering the equivalence point of the titration. Instead, a buffer solution is often used to maintain a constant pH during the titration.
Why HCL is not use to acidify KMnO4 soln in permanganometric titration?
HCl cannot be used to acidify KMnO4 solution in permanganometric titration because it will react with KMnO4 reducing it to MnO2, which interferes with the titration process and affects the accuracy of the results. Instead, dilute sulfuric acid (H2SO4) is typically used to acidify the KMnO4 solution, as it does not interfere with the redox reaction between KMnO4 and the analyte.
Why in titration of kmno4 no indicator is used?
In the titration of KMnO4, no indicator is used because KMnO4 is a self-indicating titrant. It undergoes a color change from purple to colorless (or brown) at the endpoint of the titration, which makes it unnecessary to add an external indicator. The precise endpoint can be easily detected visually, making the use of an indicator redundant.
Why kmno4 is added slowly in the titration?
KMnO4 is added slowly in titration to accurately determine the endpoint of the reaction. Rapid addition can lead to overshooting the endpoint, resulting in an inaccurate titration. Slow addition allows for better control and more precise determination of when the reaction is complete.
Why acid is added in KMnO4 titration?
Acid is added in KMnO4 titration to provide an acidic medium, which helps to stabilize the oxidizing agent MnO4-. The acidic solution also helps to prevent the premature reduction of permanganate ions and ensures a clear endpoint in the titration by facilitating the reaction with the analyte.
Balanced equation for oxalic acid and potassium permanganate?
The balanced equation for the reaction between oxalic acid (H2C2O4) and potassium permanganate (KMnO4) in acidic solution is: 5 H2C2O4 + 2 KMnO4 + 3 H2SO4 → 10 CO2 + 2 MnSO4 + 8 H2O + K2SO4
