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In the equilibrium system:

aA + bB <=> cC + dD

[A]a x [B]b

K = ___________

[C]c x [D]d

Where A, B, C and D are gases or solutions. Pure liquids and solids are not included in the equilibrium constant expression.

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13y ago
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11y ago

Law of mass action (also called 'Law of Guldberg & Waage')
Generalized reaction equation (cf. Note): aA + bB <==> pP + qQ
According to the Law of mass action:
Equilibrium constant (K>/<) is equal to [A(eq)]a.[B(eq)]b / [P(eq)]p.[Q(eq)]q
(only valid for equilibrium concentrations of A(eq), B(eq) and P(eq) and Q(eq) in the one continuous phase, ie. state of matter, the reaction is taking place in)

Note:
A and B are reactant chemical species, P and Q are product species, and a, b and p, q are the stoichiometric coëfficients of the respective reactants and products in the forward (>) and backward (<) balanced reaction equation.

Further reading
On 'Chemical equilibrium, an historical introduction' in wikipedia: look at 'Related links' just below this answer.

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13y ago

Instead of the reaction arrow which looks something like --> it will have the double equilibrium arrow, that looks kind of like an equal sign but with arrowheads on the lines (one arrow pointing each way).

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11y ago

by multiplying the products to the coefficient powers over multiplying the reactants to coefficient powers

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9y ago

chemical equlibrium problems

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Q: How can a chemical equation be used to write a equilibrium-constant expression?
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