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Ionic bonds exist between two atoms (or groups of atoms) based on their opposite electrical charge. In this case, sodium (Na) is positively charged +1 and fluorine becomes a fluoride ion (negatively charged at -1).

The reason the electrons are held this way (as opposed to being shared as in a covalent bond) is due to the relative electronegativities

of the two elements. Electonegativity is a measurement of how strongly an element 'wants' more electrons (in order to complete its valence shell).


Sodium, way over on the left side of the Periodic Table, has a very low electronegativity:

it is easier for it to lose one electron to become a cation (+ ion) and noble gas like. Fluorine on the other hand, is the electronegativity

champion - one extra electron brings it to a full stable 8 electron valence shell (octet).


Put together a willing donor and a willing recipient and you have the recipe for an ionic bond. One quick way to tell ionic bonds is to look for metals bonded to electronegative anions - Cl, Br, Fl, O, etc.



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