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Corrected: pKa i.s.o. pH

  1. Strongest Acid: hexa-Fluoro-Antimonic Acid (HSbF6 or HF.SbF5), pKa = -25

    Classified as a "Superacid". This acid will donate proton to C2H4 to form a ethane-carbocation. Compare: pKa(HClO4) = -10, HClO4 does not react with ethene.

  2. Strongest Base: Lithium Diisopropylamide [(CH3)2CH]2NLi ; pKb of 22. Classified as a "Superbase"; based upon greater than the alkalinity of pure NaOH (Sodium hydroxide, but LiOH is even stronger)

Added: (s.o.a.)

pH is a measure (or result) of the 'strength' (Ka) AND concentration [molarity] of an acid. But there is a limit to concentration of acid in water (solubility) AND the concentration of free (acidic) protons in water. That's why pH will never be much lower than -1.0 (proton concentration greater than 10.0 M rather impossible).

Addendum: Although LDA is certainly a strong base, I wouldn't call it the strongest. Sodium amide, for example, has a pKa of 38, compared to 36 for LDA. Grignard reagents have even higher pKas, somewhere around 45, and there are likely stronger bases beyond that. Bear in mind, though, that these only apply to non-aqueous solutions; in water, the strongest acid which will exist is hydronium (H3O+), and the strongest base is hydroxide (HO-).

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