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Basically there are 2 forms of iron:iron 2+ and iron 3+

Iron 2 oxide, basically is Fe2+ in order to stabilize it you need 2- which is exactly one oxygen ion

therefore we get FeO

While iron 3 oxide is Fe3+ in order to make a stable compound we need 2 Fe 3+ along with 3 O 2-

which gives us +6 and -6 therefore a stable compound which is Fe2O3

the hydrated form of iron 3 oxide is rust

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