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Petrol or gasoline is basically octane - C8H18 and when it burns in air (oxygen) it converts to Carbon Dioxide and water and heat. It is thus a chemical change.

Each carbon atom in the fuel has approximately two hydrogen atoms attached to it, and so its reduced molecular weight is a multiple about 14. In the combustion process each carbon atom is combined with two oxygen atoms of atomic weight 16, to produce CO2 with a molecular weight of 44. In addition, the two atoms of hydrogen are united with one further oxygen atom to produce water with a molecular weight of 18.

So (approximately) 14 kg of fuel reacts with 48 kg of oxygen to produce 44 kg of carbon dioxide and 18 kg of water.

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