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This is actually not a considered a chemical reaction but rather simply a dilution problem. Sodium hydroxide is considered a strong base and as such is able to completely and fully disassociate in aqueous solution. The heat evolved as a result of mixing solid sodium hydroxide with water is due to the the -OH ions incredible stability. heat is emitted as a result of the chemical species being brought to a lower energy state. This phenomena strong enough that sodium hydroxide crystals act as a powerful dessicant (it readily absorbs moisture from the air).

NaOH(s) +H2O(l)----------> Na(aq) + -OH(aq) + H2O(l)

also H2O can be found on both sides of this supposed "reaction" and thus cancel each other out

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