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It all depends on whether you'd consider only naturally occuring metals, or artificially produced one.

If artificial is OK, then just look at the latest element discovered on the Periodic Table, and home in to the heaviest element actually sythesized: ununxium, for which a single atom was produced (!) that decayed in a few millisecond.

For the naturally occuring elements, again it is mostly a case of mass (the heavier the element, the less likely it was sythesized naturally in exploding supernova, which is the way all heavier atoms were originally produced). On earth, the rarest metal is irridium, which is also the densest metal known.

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