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Basically, the more electrons that are present in an atom, the more elctron shells it will have. Look at a periodic table and you'll see Astatine has a proton number of 85 (85 protons), as the number of electrons and protons is equal, we can therefore deduce that it has 85 electrons and is the largest halogen atom. Therefore astatine MUST have the most electron shells as it has more electrons to fill them. Basically, the more electrons that are present in an atom, the more elctron shells it will have. Look at a periodic table and you'll see Astatine has a proton number of 85 (85 protons), as the number of electrons and protons is equal, we can therefore deduce that it has 85 electrons and is the largest halogen atom. Therefore astatine MUST have the most electron shells as it has more electrons to fill them.

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