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I would go for season 4 episode 3, "Minimal Loss" It's really good...Prentiss is such a strong character, she and Reid are my favourites!.....also if your a huge fan you should watch

"Demonology" (season 4)This was an essential Prentiss episode because it gave us a rare glimpse into the agent's point of view as she dealt with a friend's death and the memories it brought up from her past. "Demonology" showed viewers a very different side to the strong, self-assured agent and allowed Brewster to demonstrate some real character growth."Valhalla" (season 6)This story addressed the collision of Emily's past with her newly built life and portrayed her slow realization that she could no longer keep the two separate. It also marked a turning point in Emily's season 6 story arc, as she decided that the only the way keep her BAU family safe was to confront Doyle head-on. "Lauren" (season 6)

Along with "Demonology," this episode is a must-see for any Prentiss fan, as it explored her backstory to an extent few episodes ever did. The information we learned about her undercover work and her history with Doyle fit well with the private, cautious agent we had come to know and love. This episode served as Brewster's original exit from the series and as such, showed why Prentiss was so valuable to the team and how her loss would impact her friends.

"It Takes a Village" (season 7)"It Takes a Village" focused on Prentiss' return from the "dead" and her reunion with her team. It also brought Prentiss' past with Doyle full circle, as she helped the team bring him down and protect his son from Doyles' enemies.
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