According to the IMDG 2.5.3.2.1 The available oxygen content (%) of an organic peroxide formulation is given by the formula 16 x Σ(ni x ci/mi) Where ni = number of peroxygen groups per molecule of organic peroxide i ci = concentration (mass %) or organic peroxide i; mi = molecular mass of organic peroxide i.
there are 4 peroxy linkages...
Yes, to peroxy carboxylic acids.
The name of CH3OO is methyl peroxy.
Peroxide is an compound that can be a part of another chemical to form a molecule. Hydrogen peroxide is two hydrogen atoms attached to a peroxide molecule, forming hydrogen peroxide. Peroxide itself (O2) only exists as molecular oxygen when it is not attached to another chemical.
I'm not positive about the correct mechanism, but I can propose one that seems plausible. Oxygen can exist as a singlet or triplet species. The triplet species (O-O with 2 lone pairs and a radical on each O) is the ground state species, so unless O2 is excited, it will most likely react in this manner. Using that assumption, O2 can abstract a proton radical from flourene to form a fluorene radical (with the radical at the benzylic position). This is the initiation of a radical chain process. Next, the peroxy radical can attach to the fluorene radical (thus terminating the chain). Alternatively, another O2 molecule can attach to the fluorene radical. This peroxy fluroene radical can abstract a proton from a fluorene molecule, propogating a fluorene radical. In either case, the resulting species is a peroxy fluorene molecule. Now, you can draw a mechanism where a hydroxide anion (the reaction is run in base) pulls off the remaining benzylic proton, pushing electrons into a carbon to oxygen pi bond, and breaking the oxygen-oxygen single bond to release hydroxide. As I said, I have no evidence for this mechanism, just using my chemical knowledge and experience.
Peroxide is a good nucleophile, it might be strong enough for an addition-elimination reaction to form a peroxy acid and the alcohol. Depending on the stability of the peroxy acid, it might decompose to the carboxylic acid.
His theme song as of Royal Rumble 2009 is No More Words by EndeverafteR His theme song as of October 2010 is Another by Peroxy?gen and Dale Oliver.
The sum of the oxidation numbers of all the atoms in the peroxydisulfate ion (S2O82-) is equal to the overall charge of the ion, which is -2. Since each oxygen atom has an oxidation number of -2, and there are 8 oxygen atoms, the total contribution from oxygen is -16. This means that the sum of the oxidation numbers of the sulfur atoms must be +14 in order to balance the charge.
peroxwhy gen i think EDIT: Peroxwhy?gen is Jeff's band's name. It currently has only two members: Jeff Hardy and JR Merill.
We can buy Potassium Mono Persulfate also known as CAROAT manufactured by German manufacturer from M/s. United Initiators Gmbh & Kg. - Germany and also from its Indian Stockist M/s. Madhu Chemicals - Mumbai. (Tel. No. +91 22 67412824 / 67419980).
CH3CO3H is the chemical formula for acetic percarbonic acid, which is used as a bleaching agent in some cleaning products. It is a peroxy acid with a structure similar to hydrogen peroxide, but with an additional acetyl (CH3CO) group.
Peroxybenzoic acid is a simple peroxy acid. It may be synthesized from benzoic acid and hydrogen peroxide,[2] or by the treatment of benzoyl peroxide with sodium methoxide, followed by acidification.[3]Like other peroxyacids, it may be used to generate epoxides, such as styrene oxide from styrene:[4]