No, the iPod will not charge if it is off. The iPod must be on
for it to charge.
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It will charge faster if the primary ignition is off and the
switch is flipped off, but it does not have to be completely off to
charge.
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You can charge it whilst it's on or off.
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You can charge your iPad either way - it doesn't need to be on
or off. However, the most effective way is to charge your iPad when
it's off. It will charge much faster.
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I've never heard of a "charge off bank" but I do know that a
charge off account at a bank is where they bank has listed a loan
as "uncollectable" and is probably reporting it to the credit
bureau as a charge off or "bad debt". Hope this helps