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It does not.

Surface tension of a liquid exists due to the fact that the molecules are at a higher potential when they are at the surface than when they are submerged in the bulk. A liquid system then tends to minimize its total free energy in such a way that the surface molecules, given the opportunity, "dive". Other surface molecules must replace a diving molecule on the surface and this makes the surface shrink laterally. Correspondingly, when the surface is stretched, molecules that have a smaller potential in the bulk are lifted to the surface so that work must be done and a force is required to do the stretching.

On a solid, the molecules are constrained so that they cannot move freely. Hence, they cannot "dive". For the same reason they do not move laterally and there is no mechanism that could transfer the potential difference in the direction perpendicular to a surface into actions parallel to it.

In capillary processes it often appears as if a solid would have a surface tension. Many phenomena can be nicely explained that way, but this is only because there are forces acting between a solid and a liquid, and it is the liquid that is able to adjust to them.

In physics literature you would find "Shuttleworth's equation" relating the surface tension with the surface energy on a solid. This, however, has recently been shown to be incorrect (Surface Science, 603(1): 97-101.

LM

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13y ago
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12y ago

Surface tension is the result of an inward pull among the molecules on the surface closer together.

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9y ago

Liquids - yes. Gases - no.

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15y ago

No.

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10y ago

Nope. sorry

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9y ago

Yes

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Q: Do crystalline solids have high surface tension?
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