A cyclic molecule or ion having different resonating structure follows Hückel's rule when the number of its π-electrons equals 4n+2 where n is zero or any positive integer.
Example
(4 x (0)) + 2 = 2 π electrons
(4 x (1)) + 2 = 6 π electrons
(4 x (2)) + 2 = 10 π electrons
etc
Taking benzene as an example, it has 3 double bonds so 6 π electrons (2 electrons for each double bond) thus it fits Huckels rule and therefore is aromatic. If the molecule is an ion and has a negative charge, the negative charge is also counted as 2 π electrons. Positive charges on a cyclic molecule are ignored.
The Huckels rule of aromaticity states that a compound is particularly stable if all of its bonding molecular orbitals are filled with paired electrons.
Huckel's rule dictates the chemical stability of a planar, aromatic ring with resonance, as in a benzene (C6H6) molecule.
because it obeys huckle rule of aromaticity.
No - although it has sufficient electrons to obey the Huckel rule (4n+2) pi electrons. The two olefins in the ring are cross-conjugated through the carbonyl groups. The lack of proper conjugation precludes aromaticity. The non aromaticity is evidenced by different bond-lengths around the ring
GIUNNNSLLJTJOHNSON
as because in case of tropylium cation extra stability arises from the attainment of aromaticity as well as extensive conjugation.It contains 6π electrons which is according to Huckel's rule indicate towards the aromatic compound as well as the system is also a resonance stabilized because of delocalisation
Huckels rule. 4n + 2 whereby n is any integer for example 1,2,3 etc. Aromatic compounds will obey huckels rule:- (4 x (1)) + 2 = 6 (4 x (2)) + 2 = 10 (4 x (3)) + 2 = 14 Taking benzene as an example...is it aromatic? Is a six membered ring with 3 double bonds, so 6pi electrons thus obeys huckels rule and is aromatic. Negative charges also count as 2pi electrons and positive charges on a molecule are ignored entirely.
Huckel's rule is used in aromaticity by stating that monocyclic systems are aromatic. This will happen if there are delocalized electrons.
because it obeys huckle rule of aromaticity.
Illustrate the difference between aromaticity and antiaromaticity with appropriate examples?
No - although it has sufficient electrons to obey the Huckel rule (4n+2) pi electrons. The two olefins in the ring are cross-conjugated through the carbonyl groups. The lack of proper conjugation precludes aromaticity. The non aromaticity is evidenced by different bond-lengths around the ring
GIUNNNSLLJTJOHNSON
An aromatic compound is a compound in organic chemistry which exhibits aromaticity.
Pyrimidine is one ring structure with 4 carbons and 2 nitrogens, linked together in a ring, with a carbon located between the nitrogens. It follows Hucke's rule for aromaticity, and therefore is a NN-heterocyclic aromatic hydrocarbon.
Yes
Yes
k
Positive correlation
as because in case of tropylium cation extra stability arises from the attainment of aromaticity as well as extensive conjugation.It contains 6π electrons which is according to Huckel's rule indicate towards the aromatic compound as well as the system is also a resonance stabilized because of delocalisation