To delete photos from iPod touch:
In iTunes, select the device icon in the Devices list on the
left. Click the Photos tab in the resulting window.
Choose "Sync photos from."
On a Mac, choose iPhoto or Aperture from the pop-up menu.
On a Windows PC, choose Photoshop Album or Photoshop Elements
from the pop-up menu.
Choose "Selected albums" and deselect the albums or collections
you want to delete.
Click Apply.