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Syncing photos allows you to view pix you've chosen on your computer on you iPod.
No, it won't, unless you are syncing from a different computer, then yes it will.
The cast of That Syncing Feeling - 2012 includes: Sarah Haworth
The iPhone because Apple's software for syncing, which is iTunes, is native to the Mac and is able to manage your syncing smoothly and easily.
Assuming you are using iTunes: view the properties of the connected iPod. There should be a setting related to automatic syncing. Select manual.