This is the solvent in the ink (dye). Toluol and Xylol were
common synthetics used as solvents but have now been replaced by
safer chemicals such as cyclic alkylene carbonates. (this is the
sweet smelling gas you detect) The solvent is the substance into
which the dye is diluted. Water can also act as a solvent in ink.
When released from the marker, the solvent evaporates and leaves
the solid ink on the surface