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Helium nuclei, which are abundant throughout the universe both as radioactive-decay products and as key participants in stellar fusion reactions. Alpha particles can also be generated in the laboratory, either by ionizing helium or from nuclear reactions. They expend their energy rapidly as they pass through matter, primarily by taking part in ionization processes, and consequently have short penetration ranges. Numerous technological applications of alpha particles can be found in fields as diverse as medicine, space exploration, and geology. Alpha particles are also major factors in the health concerns associated with nuclear waste and other radiation hazards.
The helium nucleus, or alpha particle (α), with mass 4.00150 atomic mass units (u) and charge +2, is a strongly bound cluster of two protons (p) and two neutrons (n). Its stability is evident from mass-energy conservation in the hypothetical fusion reaction 2p + 2n → α. The product mass (= 4.00150 u) is less than the reactant mass (= 2 × 1.00728 u + 2 × 1.00866 u) by 0.03038 u. By using Einstein's relation E = mc2 (where c is the speed of light), this decrease in mass m (the alpha-particle binding energy) is equivalent to 28.3 MeV of energy E. The enormous magnitude of this energy is reflected in the fact that the fusion transformation of hydrogen into helium is the main process responsible for the Sun's energy. See also Conservation of energy; Energy; Helium; Nuclear binding energy; Proton-proton chain;
Alpha radioactivity
Coulombic repulsion between the protons within a nucleus leads to increasingly larger ratios of neutron number N to proton number Z for stable nuclei, as the mass numbers increase. Neutron-deficient nuclei can improve their N/Z ratios by means of alpha decay. The decay occurs because the parent nucleus has a total mass greater than the sum of the masses of the daughter nucleus and the alpha particle. The energy converted from mass energy to kinetic energy, called the Q value, is shared between the daughter nucleus and the alpha particle in accordance with the conservation of momentum. Thus, each radioactive alpha-emitting nuclide emits the alpha with a characteristic kinetic energy, which is one fingerprint in identification of the emitter. See also
There are three major natural series, or chains, through which isotopes of heavy elements decay by successions of alpha decays. Within these series, and with all reaction-produced alpha emitters as well, each isotope decays with a characteristic half-life and emits alpha particles of particular energies and intensities. The presence of these radioactive nuclides in nature depends upon either a continuous production mechanism, for example the interaction of cosmic rays with the atmosphere, or extremely long half-lives of heavy radioactive nuclides produced in past cataclysmic astrophysical events, which accounts for uranium and thorium ores in the Earth. The relative abundances of uranium-238, uranium-235, and their stable final decay products in ores of heavy elements can be used to calculate the age of the ore, and presumably the age of the Earth. See also Geochronometry.
In addition to the study of alpha-particle emitters that appear in nature, alpha decay has provided a useful tool to study artificial nuclei, which do not exist in nature due to their short half-lives. Alpha decay is a very important decay mode for nuclei far from stability with a ratio of protons to neutrons that is too large to be stable, especially for nuclei with atomic mass greater than 150 u. Because of the ease of detecting and interpreting decay alpha particles, their observation has aided tremendously in studying these nuclei far from stability, extending the study of nuclei to the very edge of nuclear existence. Nuclear structure information for more than 400 nuclides has been obtained in this way. In addition, fine structure peaks appear in the alpha-particle spectra for many of these nuclides; each such fine structure peak gives similar information about an excited state in the daughter nucleus.
Interactions with matter
By virtue of their kinetic energy, double positive charge, and large mass, alpha particles follow fairly straight paths in matter, interacting strongly with atomic electrons as they slow down and stop. These electrons may be excited to higher energy states in their host atoms, or they may be ejected, forming ion pairs in which the initial host atom becomes positively charged and the electron leaves. The more energetic ejected electrons, known as delta electrons, cause considerable secondary ionization, which accounts for 60–80% of the total ionization. A cascade of processes occurs along the alpha particle's track, leading to tens of thousands of disruptive events per alpha particle. See also Radiation damage to materials.
The amount of energy expended by an alpha particle to form a single ion pair in passing through a medium is nearly independent of the alpha particle's energy, but it depends strongly on the absorbing medium. While it takes about 35 eV in air and 43 eV in helium to form an ion pair, an energy of only 2.9 eV is required in germanium and 3.6 eV in silicon. The energies expended in gases are roughly correlated to their ionization potentials. For germanium, silicon, and other semiconductors, the lower ion pair energy is, effectively, the amount required to raise an electron to the conduction band. See also Ionization potential; Semiconductor.
The distance (or range) that an alpha particle travels before it stops depends both on the energy of the particle and on the absorbing medium. The passage of alpha particles through silicon is a particularly important example. The semiconductor industry now produces chips so small that alpha particles from contaminants in the packaging materials can disrupt the memory-array areas of the chips, a serious problem which has been researched in considerable detail. See also Integrated circuits; Radiation hardening.
In biological systems, the ionization and excitation produced by alpha particles can damage or kill cells. By rupturing chemical bonds and forming highly reactive free radicals, alpha particles can be far more destructive than other forms of radiation which interact less strongly with matter. See also Charged particle beams; Radiation chemistry.
Applications
In the promising medical field of charged-particle radiotherapy, alpha particles are useful in the treatment of inaccessible tumors and vascular disorders. The ionizing power of alpha particles is concentrated near the ends of their paths. Thus they can deliver destructive energy to a tumor while doing little damage to nearby healthy tissue. With proper acceleration, positioning, and dosage, the energy can be delivered so precisely that alpha-particle radiotherapy is uniquely suited for treating highly localized tumors near sensitive normal tissue (for example, the spinal cord). See also Radiology.
The element-specific energies of backscattered (Rutherford-scattered) alpha particles are used in remote probes to analyze the mineral composition of geological formations. In particular, alpha particles scattered by light elements transfer more energy than those scattered by heavy elements. In another alpha-particle device, the energy from 238Pu alpha decay is reliably harnessed in batteries based on the Brayton cycle, and used to power scientific equipment left on the Moon. Large power systems of this type are contemplated for use in space stations. See also Ion-solid interactions; Nuclear battery.
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(alpha ray, alpha radiation) positively charged particulate ionizing radiation consisting of helium nuclei (two protons and two neutrons) traveling at high speeds. These rays are emitted from the nucleus of an unstable element.
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| Wikipedia: Alpha particle |
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| Composition: | 2 protons, 2 neutrons |
| Statistical behavior: | Boson |
| Symbol(s): | α, α2+, He2+ |
| Mass: | 6.64465620(33)×10−27 kg |
| Electric charge: | 2 e |
| Spin: | 0[2] |
Alpha particles (named after and denoted by the first letter in the Greek alphabet, α) consist of two protons and two neutrons bound together into a particle identical to a helium nucleus; hence, it can be written as He2+ or 42He2+. They have a net spin of zero, and normally a total energy of about 5 MeV. They are a highly ionizing form of particle radiation, and have low penetration.
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When an atom emits an alpha particle, the atom's mass number decreases by four due to the loss of the four nucleons in the alpha particle. The atomic number of the atom goes down by exactly two, as a result of the loss of two protons – the atom becomes a new element. Examples of this are when uranium becomes thorium, or radium becomes radon gas due to alpha decay.
Alpha particles are commonly emitted by all of the larger radioactive nuclei such as uranium, thorium, actinium, and radium, as well as the transuranic elements. Unlike other types of decay, alpha decay as a process must have a minimum-size atomic nucleus which can support it. The smallest nuclei which have to date been found to be capable of alpha emission are the lightest nuclides of tellurium (element 52), with mass numbers between 106 and 110. The process of emitting an alpha sometimes leaves the nucleus in an excited state, with the emission of a gamma ray removing the excess energy.
In contrast to beta decay, the fundamental interactions responsible for alpha decay are a balance between the electromagnetic force and nuclear force. Alpha decay results from the Coulomb repulsion[2] between the alpha particle and the rest of the nucleus, which both have a positive electric charge, but which is kept in check by the nuclear force. In classical physics, alpha particles do not have enough energy to escape the potential well from the strong force inside the nucleus (this well involves escaping the strong force to go up one side of the well, which is followed by the electromagnetic force causing a repulsive push-off down the other side).
However, the quantum tunnelling effect allows alphas to escape even though they do not have enough energy to overcome the nuclear force. This is allowed by the wave nature of matter, which allows the alpha particle to spend some of its time in a region so far from the nucleus that the potential from the repulsive electromagnetic force has fully compensated for the attraction of the nuclear force. From this point, alpha particles can escape, and in quantum mechanics, after a certain time, they do so.
The energy of the alpha emitted is mildly dependent on the half-life for the emission process, with many orders of magnitude differences in half-life being associated with energy changes of less than 50% (see alpha decay). The energy of alpha particles emitted varies, with higher energy alpha particles being emitted from larger nuclei, but most alpha particles have energies of between 3 and 7 MeV (mega-electron-volts), corresponding to extremely long to extremely short half-lives of alpha-emitting nuclides, respectively.
This energy is a substantial amount of energy for a single particle, but their high mass means alpha particles have a lower speed (with a typical kinetic energy of 5 MeV, the speed is 15,000 km/s which is 5% of the speed of light) than any other common type of radiation (β particles, neutrons, etc). γ rays, being an electromagnetic radiation, move at the speed of light. Because of their charge and large mass, alpha particles are easily absorbed by materials, and they can travel only a few centimetres in air. They can be absorbed by tissue paper or the outer layers of human skin (about 40 micrometres, equivalent to a few cells deep).
Because of the short range of absorption, alphas are not generally dangerous to life unless the source is ingested or inhaled, but then they become extremely dangerous. Because of this high mass and strong absorption, if alpha emitting radionuclides do enter the body (if the radioactive material has been inhaled or ingested), alpha radiation is the most destructive form of ionizing radiation. It is the most strongly ionizing, and with large enough doses can cause any or all of the symptoms of radiation poisoning. It is estimated that chromosome damage from alpha particles is about 100 times greater than that caused by an equivalent amount of other radiation. The alpha emitter polonium-210 is suspected of playing a role in lung cancer and bladder cancer related to tobacco smoking.[3]
Not only do alphas themselves cause damage, but approximately equal ionization is caused by the recoiling nucleus after alpha emission, and this energy may in turn be especially damaging to genetic material, since the positive cations of many soluble transuranic elements which emit alphas, are chemically attracted to the net negative charge of DNA, causing the recoiling atomic nucleus to be in close proximation to the DNA.
Rutherford originally separated out radiation into alpha, beta, and gamma components, based on its penetration of objects and its ability to cause ionization. Alpha rays were defined by their lowest penetration of ordinary objects.
Rutherford's work also included measurements of the ratio of an alpha particle's mass to charge, allowing him to hypothesize that that alpha particles were helium nuclei (deuterium nuclei, which have the same mass to charge, were not then known).[4] That alphas were helium nuclei was finally proven by allowing alpha particles to penetrate the thin glass into a vacuum tube, which was then energized to provide a gas discharge tube glow. The spectrum produced turned out to be that of helium.
Because alpha particles occur naturally, but can have energy high enough to participate in a nuclear reaction, study of them led to much early knowledge of nuclear physics. Physicist Ernest Rutherford used alpha particles emitted by radium bromide to infer that J. J. Thomson's Plum pudding model of the atom was fundamentally flawed. In Rutherford's gold foil experiment conducted by his students Hans Geiger and Ernest Marsden, a narrow beam of alpha particles was established, passing through very thin (a few hundred atoms thick) gold foil. The alpha particles were detected by a zinc sulfide screen, which emits a flash of light upon an alpha particle collision. Rutherford hypothesized that, assuming the "plum pudding" model of the atom was correct, the positively charged alpha particles would be only slightly deflected, if at all, by the dispersed positive charge predicted.
It was found that some of the alpha particles were deflected at much larger angles than expected, (at a suggestion by Rutherford to check it) it was found that some even bounced almost directly back. Although most of the alpha particles went straight through as expected, Rutherford commented that the few particles that were deflected was akin to shooting a fifteen inch shell at tissue paper only to have it bounce off, again assuming the "plum pudding" theory was correct. It was determined that the atom's positive charge was concentrated in a small area in its center, making the positive charge dense enough to deflect any positively charged alpha particles that came close to what was later termed the nucleus. Note: it was not known at the time that alpha particles were themselves nuclei nor was the existence of protons or neutrons known. Rutherford's experiment led to the Bohr model (named for Niels Bohr) and later the modern wave-mechanical model of the atom.
In computer technology, dynamic random access memory (DRAM) "soft errors" were linked to alpha particles in 1978 in Intel's DRAM chips. The discovery led to strict control of radioactive elements in the packaging of semiconductor materials, and the problem was largely considered to be "solved".[citation needed]
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